- Số mol NaOH=0,2a

-Số mol Ba(OH)₂=0,2a

- Tổng số mol OH^-=0,6a

\(\left[OH^-\right]=\dfrac{0,6a}{0,3}=2a\left(M\right)\)

pH=14+lg\(\left[OH^-\right]\)suy ra: 13=14+lg\(\left[OH^-\right]\)suy ra:

lg\(\left[OH^-\right]\)=-1 suy ra: \(\left[OH^-\right]\)=10^-1=0,1M. Vậy:

2a=0,1 suy ra: a=0,05M

- Số mol OH^-=0,6a=0,6.0.05=0,03mol

- Số mol H⁺=0,175.0,2.2=0,07mol

H⁺+OH^-\(\rightarrow\)H₂O

- Số mol H⁺ dư= 0,07-0,03=0,04mol

- Tổng thể tích=100+200+200=500ml=0,5 lít

\(\left[H^+\right]=\dfrac{0,04}{0,5}=0,08\left(M\right)\)

pH=-lg\(\left[H^+\right]\)=-lg(0,08)\(\approx\)1,1

Fe  + H₂SO₄ →  FeSO₄  + H₂ (1)

10FeSO₄   +   2KMnO₄   + 8H₂SO₄ → 5Fe₂(SO₄)₃   +  K₂SO₄ +   2MnSO₄  +  8H₂O(2)

nKMnO₄ = 0,1.0,3 = 0,03 mol , nFeSO₄ = 0,03.5 = 0,15 mol

=> nH₂SO₄ cần dùng cho (2) = 4 KMnO4 = 0,12 mol

nnH₂SO₄ cần dùng cho (1) = nFeSO₄ = 0,15 mol 

=> Tổng số mol H₂SO₄ cần dùng = 0,12 + 0,15 = 0,27 mol

\(n_{SO_2}=\dfrac{4,48}{22,4}=0,2mol\)

\(\Rightarrow n_{H_2SO_4}=2n_{SO_2}=2\cdot0,2=0,4mol\)

\(\Rightarrow n_{SO_4^{2-}}=n_{H_2SO_4}=0,4mol\Rightarrow m_{SO_4^{2-}}=0,4\cdot96=38,4g\)

\(m=m_{SO_4^{2-}}+m_{hhX}=38,4+6,7=45,1g\)

a,\(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)

PTHH: CuO + H₂SO₄ →CuSO₄ + H₂O

Mol:     0,25      0,25         0,25

\(m_{ddH_2SO_4}=\dfrac{0,25.98.100}{19,6}=125\left(g\right)\)

b,m_{dd sau pứ} = 20+125 = 145 (g)

\(C\%_{ddCuSO_4}=\dfrac{0,25.160.100\%}{145}=27,59\%\)

\(Cu+H_2SO_4\rightarrow CuSO_4+H_2\)
0,3125    0,3125   0,3125        (mol)
a)\(n_{Cu}=\dfrac{20}{64}=0,3125\left(mol\right)\)
\(m_{H_2SO_4}=0,3125.98=30,625\left(g\right)\)
\(m_{ddH_2SO_4}=\dfrac{30,625}{19,6}.100=156,25\left(g\right)\)
b)\(m_{CuSO_4}=0,3125.160=50\left(g\right)\)
\(m_{ddCuSO_4}=20+156,25=176,25\left(g\right)\)
\(C\%_{CuSO_4}=\dfrac{50}{176,25}.100\approx28,37\%\)

Bài 1:

SO₃ + H₂O → H₂SO₄

Gọi x là sô smol của SO₃

\(\Rightarrow m_{SO_3}=80x\left(g\right)\)

Theo pT: \(n_{H_2SO_4}tt=n_{SO_3}=x\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4}tt=98x\left(g\right)\)

\(m_{ddH_2SO_4.20\%}=100\times1,14=114\left(g\right)\)

\(\Rightarrow m_{H_2SO_4.20\%}=114\times20\%=22,8\left(g\right)\)

\(m_{H_2SO_4.25\%}=m_{H_2SO_4}tt+m_{H_2SO_4.20\%}=98x+22,8\left(g\right)\)

\(m_{ddH_2SO_4.25\%}=m_{SO_3}+m_{ddH_2SO_4.20\%}=80x+114\left(g\right)\)

\(C\%_{ddH_2SO_4.25\%}=\frac{98x+22,8}{80x+114}\times100\%=25\%\)

\(\Leftrightarrow\frac{98x+22,8}{80x+114}=0,25\)

\(\Rightarrow98x+22,8=20x+28,5\)

\(\Leftrightarrow78x=5,7\)

\(\Leftrightarrow x=\frac{5,7}{78}=\frac{19}{260}\left(mol\right)\)

Vậy \(n_{SO_3}=\frac{19}{260}\left(mol\right)\Rightarrow m_{SO_3}=\frac{19}{260}\times80=5,85\left(g\right)\)

thanks bạn

a) \(\left\{{}\begin{matrix}160n_{Fe_2O_3}+80n_{CuO}=24\\n_{Fe_2O_3}=n_{CuO}\end{matrix}\right.\Rightarrow n_{Fe_2O_3}=n_{CuO}=0,1\)

\(\left\{{}\begin{matrix}\%m_{Fe_2O_3}=\dfrac{160.0,1}{24}.100\%=66,67\%\\\%m_{CuO}=\dfrac{80.0,1}{24}.100\%=33,33\%\end{matrix}\right.\)

PTHH: Fe₂O₃ + 3H₂SO₄ --> Fe₂(SO₄)₃ + 3H₂O

              0,1------>0,3-------->0,1

            CuO + H₂SO₄ --> CuSO₄ + H₂O

              0,1-->0,1---------->0,1

n_CuSO4 = 0,1 (mol)

n_Fe2(SO4)3 = 0,1 (mol)

=> m = 0,1.160 + 0,1.400 = 56(g)

b) \(m_{H_2SO_4\left(pthh\right)}=\left(0,3+0,1\right).98=39,2\left(g\right)\)

=> m_{H2SO4(thực tế)} = \(\dfrac{39,2.125}{100}=49\left(g\right)\)

c) \(n_{H_2SO_4}=\dfrac{49}{98}=0,5\left(mol\right)\)

=> n_BaSO4 = 0,5 (mol)

=> m_BaSO4 = 0,5.233 = 116,5(g)

\(n_{NaOH}=\frac{160.20}{100.40}=0,8\left(mol\right)\\ PTHH:2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ m_{H_2SO_4}=\left(\frac{0,8}{2}\right).98=39,2\left(g\right)\\ m_{ddH_2SO_4}=\frac{39,2.100}{10}=392\left(g\right)\\ m_{ddspu}=160+392=552\left(g\right)\\ C\%_{ddX}=\frac{0,4.142}{552}.100\%=10,29\left(\%\right)\)

$n_{Ba(OH)_2} = 0,3(mol)$
$n_{H_2SO_4} = 0,2(mol)$
$Ba(OH)_2 + H_2SO_4 \to BaSO_4 + 2H_2O$
$n_{Ba(OH)_2} > n_{H_2SO_4}$ nên $Ba(OH)_2$ dư

$n_{BaSO_4} = n_{H_2SO_4} = 0,2(mol)$
$m_{BaSO_4} =  0,2.233 = 46,6(gam)$

PTHH: \(Ba\left(OH\right)_2+H_2SO_4\rightarrow BaSO_4\downarrow+2H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{Ba\left(OH\right)_2}=0,15\cdot2=0,3\left(mol\right)\\n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Bazơ còn dư

\(\Rightarrow n_{BaSO_4}=0,2\left(mol\right)\) \(\Rightarrow m_{BaSO_4}=0,2\cdot233=46,6\left(g\right)\)