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a) PTHH: \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\)
\(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)
b) Ta có: \(n_{FeCl_3}=0,3\cdot0,5=0,15\left(mol\right)\)
\(\Rightarrow n_{NaOH}=0,45mol\) \(\Rightarrow V_{ddNaOH}=\dfrac{0,45}{0,25}=1,8\left(l\right)\)
c) Theo PTHH: \(n_{NaCl}=n_{NaOH}=0,45mol\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,45}{2,1}\approx0,21\left(M\right)\)
(Coi như thể tích dd thay đổi không đáng kể)
d) Theo PTHH: \(n_{H_2SO_4}=\dfrac{3}{2}n_{Fe\left(OH\right)_3}=\dfrac{3}{2}n_{FeCl_3}=0,225mol\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,225\cdot98}{20\%}=110,25\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{110,25}{1,14}\approx96,71\left(ml\right)\)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)
a) FeO + 2 HCl -> FeCl2 + H2O
FeCl2 + 2 NaOH -> Fe(OH)2 (kết tủa) + 2 NaCl
m(rắn)=m(kt)=mFe(OH)2=24(g)
=> nFe(OH)2= 24/90= 8/45 (mol)
=> nFeO=nFeCl2=nFe(OH)2= 8/45(mol)
=>m=mFeO=8/45 . 72=12,8(g)
nHCl=2.nFeCl2=2.nFe(OH)2=2. 8/45 = 16/45(mol)
-> VddHCl= (16/45)/ 1= 16/45 (l)= 355,556(ml)
HCl + AgNO3 ➜ AgCl↓ + HNO3
\(n_{HCl}=0,2\times2=0,4\left(mol\right)\)
\(n_{AgNO_3}=0,3\times2=0,6\left(mol\right)\)
Theo PT: \(n_{HCl}=n_{AgNO_3}\)
Theo bài: \(n_{HCl}=\dfrac{2}{3}n_{AgNO_3}\)
Vì \(\dfrac{2}{3}< 1\) ⇒ dd HCl hết, dd AgNO3 dư
Theo PT: \(n_{AgCl}=n_{HCl}=0,4\left(mol\right)\)
\(\Rightarrow m_{AgCl}=0,4\times143,5=57,4\left(g\right)\)
Dung dịch B gồm: AgNO3 dư và HNO3
Theo PT: \(n_{AgNO_3}pư=n_{HCl}=0,4\left(mol\right)\)
\(\Rightarrow n_{AgNO_3}dư=0,6-0,4=0,2\left(mol\right)\)
Theo PT: \(n_{HNO_3}=n_{HCl}=0,4\left(mol\right)\)
\(\Sigma n_{ctB}=n_{AgNO_3}dư+n_{HNO_3}=0,2+0,4=0,6\left(mol\right)\)
\(\Sigma m_{ddB}=0,2+0,3=0,5\left(l\right)\)
\(\Rightarrow C_{M_{ddB}}=\dfrac{0,6}{0,5}=1,2\left(M\right)\)
HCl + AgNO3 ➜ AgCl↓ + HNO3
\(n_{HCl}=0,2\times2=0,4\left(mol\right)\)
\(n_{AgNO_3}=0,3\times2=0,6\left(mol\right)\)
Theo PT: \(n_{HCl}=n_{AgNO_3}\)
Theo bài: \(n_{HCl}=\dfrac{2}{3}n_{AgNO_3}\)
Vì \(\dfrac{2}{3}< 1\) ⇒ dd HCl hết, dd AgNO3 dư
Theo PT: \(n_{AgCl}=n_{HCl}=0,4\left(mol\right)\)
\(\Rightarrow m_{AgCl}=0,4\times143,5=57,4\left(g\right)\)
Dung dịch B gồm: AgNO3 dư và HNO3
\(\Sigma m_{ddB}=0,2+0,3=0,5\left(l\right)\)
Theo PT: \(n_{HNO_3}=n_{HCl}=0,4\left(mol\right)\)
Theo PT: \(n_{AgNO_3}pư=n_{HCl}=0,4\left(mol\right)\)
\(\Rightarrow n_{AgNO_3}dư=0,6-0,4=0,2\left(mol\right)\)
\(\Sigma n_{ctB}=n_{AgNO_3}dư+n_{HNO_3}=0,2+0,4=0,6\left(mol\right)\)
\(\Rightarrow C_{M_{ddB}}=\dfrac{0,6}{0,5}=1,2\left(M\right)\)